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Borane dimethyl sulfide complex solution, 2.0 M in THF

Code: 192120-100ML D2-231

Application

Reactant used as a regioselective reducing agentReactant involved in: Hydroboration / oxidationSynthesis of cage compounds

Borane dimethyl sulfide complex ...


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Your Price
£70.20 100ML
£84.24 inc. VAT

Application

Reactant used as a regioselective reducing agentReactant involved in: Hydroboration / oxidationSynthesis of cage compounds

Borane dimethyl sulfide complex (BMS) solution may be used in the following studies:One-pot conversion of alkynes into 1,2-diols.Preparation of iminopentitols. Reduction of representative organic functional groups, such as esters, nitriles and amides. Used along with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. Asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.

General description

Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.

Packaging

100, 800 mL in Sure/Seal™

concentration2.0 M in THF
density0.855 g/mL at 25 °C
formliquid
InChI keyRMHDLBZYPISZOI-UHFFFAOYSA-N
InChI1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
Quality Level200
reaction suitabilityreagent type: reductant
SMILES stringB.CSC
storage temp.2-8°C
Cas Number13292-87-0
Hazard Class4.3
Un Number3399
Pack GroupI
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