763039-1G Display Image

XantPhos Pd G3, 95%

Code: 763039-1G D2-231

Application

XantPhos Pd G3 may be used in the following processes:Negishi cross-coupling reaction during the synthesis of palmerolides.Aminocarbonylation of heteroaryl bromid...


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Your Price
£118.00 1G
£141.60 inc. VAT

Application

XantPhos Pd G3 may be used in the following processes:Negishi cross-coupling reaction during the synthesis of palmerolides.Aminocarbonylation of heteroaryl bromides with carbon monoxide (CO) in the presence of triethylamine. Coupling between polyglycosyl thiols and aglycon halides by C-S bond formation.

General description

XantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Packaging

1, 5 g in glass bottle

250 mg in glass bottle

assay95%
featuregeneration 3
formsolid
functional groupphosphine
InChI keyAJVXPGQYAKUTGX-UHFFFAOYSA-M
InChI1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
mp164-167 °C (decomposition)
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalystreaction type: Cross Couplings
SMILES stringCS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC3(C)c4cccc(P(c5ccccc5)c6ccccc6)c4Oc7c(cccc37)P(c8ccccc8)c9ccccc9
Code
Description
Unit Size
List Price
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763039-250MG
Unit:250MG
List Price: £38.20
Source:List Price
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763039-5G
Unit:5G
List Price: £506.00
Source:List Price
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