80833-10G Display Image

18-CROWN-6

Code: 80833-10G D2-231

Application

18-Crown-6 may be used as a complexing agent, along with the mobile phase for the separation of alkali and alkaline earth metal and amine cations and its applicat...


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£88.90 10G

Application

18-Crown-6 may be used as a complexing agent, along with the mobile phase for the separation of alkali and alkaline earth metal and amine cations and its application for the direct analysis of ammonia from nitrogenase is studied. It may also be used as a complexing agent in the determination of inorganic and organic anions, alkali, alkaline earth and transition metal cations by capillary electrophoresis using contactless conductometric detector.

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Can be useful as phase-transfer catalysts.

General description

18-Crown-6 belongs to the class of Crown ethers, a group of macrocyclic polyethers, which have become valuable tools in organic synthesis, since they can solvate alkali, alkaline-earth and transition-metal cations in nonpolar, aprotic solvents. 18-Crown-6 is found to be most suitable for complexing with K+, NH4+ and Rb+ cations.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Linkage

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Other Notes

Macrocyclic polyethers with repeating (-CH2CH2O) units. The compounds are ionophoric (form stable complexes with cations).

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assay≥99.0% (GC)
cation tracesCd: ≤1 mg/kg, Ca: ≤1 mg/kg, Fe: ≤1 mg/kg, Mg: ≤1 mg/kg, Bi: ≤1 mg/kg, NH4+: ≤10 mg/kg, Mo: ≤1 mg/kg, Al: ≤1 mg/kg, Ni: ≤1 mg/kg, Cr: ≤1 mg/kg, Na: ≤20 mg/kg, K: ≤20 mg/kg, Zn: ≤1 mg/kg, Pb: ≤1 mg/kg, Co: ≤1 mg/kg, Ba: ≤1 mg/kg, Cu: ≤1 mg/kg, Mn: ≤1 mg/kg, Sr: ≤1 mg/kg, Li: ≤1 mg/kg
formsolid
InChI keyXEZNGIUYQVAUSS-UHFFFAOYSA-N
InChI1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
mp42-45 °C (lit.)
Quality Level100
SMILES stringO1CCOCCOCCOCCOCCOCC1
technique(s)ion chromatography: suitable
Cas Number17455-13-9
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