708682-500MG Display Image

RuCl[(R,R)-TsDPEN](mesitylene), 90%

Code: 708682-500MG D2-231

Application

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:(2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one...


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£115.00 500MG
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Application

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:(2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Packaging

500 mg in amber glass bottle

assay90%
formsolid
InChI keyXBNBOGZUDCYNOJ-AGEKDOICSA-M
InChI1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
mp241-249 °C
Quality Level100
SMILES stringCc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
storage temp.2-8°C
Cas Number174813-82-2
This product has met the following criteria: