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Tris[2-phenylpyridinato-C2,N]iridium(III), 99%

Code: 688096-250MG D2-231

Application

Put to elegant use by Stephenson for the reduction of alkyl, alkenyl and aryl iodides in the presence of visible light. Intramolecular reductive cyclizations were...


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£344.00 250MG
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Application

Put to elegant use by Stephenson for the reduction of alkyl, alkenyl and aryl iodides in the presence of visible light. Intramolecular reductive cyclizations were also achieved with this catalyst.Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

Learn More at the Professor and Product Portal of Professor Corey Stephenson.

General description

Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.

Packaging

250 mg in glass insert

assay97%
descriptionfac-Tris[2-phenylpyridinato-C2,N]iridium(III)
fluorescenceλex 340 nm; λem 512 nm in chloroform
formpowder
InChI keyQKBWDYLFYVXTGE-UHFFFAOYSA-N
InChI1S/3C11H8N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-6,8-9H;
OLED device performanceITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al Color: green Max. Luminance: 207839 Cd/m2 Max. EQE: 21.6 % Turn-On Voltage: 2.1 V, ITO/NPD/CBP:Ir(ppy)3 (6%)/Alq3/Mg:Ag Color: green Max. Luminance: 100000 Cd/m2 Max. EQE: 8 % Turn-On Voltage: 4.3 V, ITO/HMPD/TAZ:Ir(ppy)3 (7%)/Alq3/Al:Li Color: green Max. Luminance: 4000 Cd/m2 Max. EQE: 15 %, ITO/TCTA/Ir(ppy)3/Bphen/LiF/Al Color: green Max. Luminance: 300000 Cd/m2 Max. EQE: 19 % Turn-On Voltage: 2.6 V
orbital energyHOMO 5.6 eV, LUMO 3 eV
photocatalyst activation425 nm
Quality Level100
reaction suitabilityreaction type: Photocatalysis, core: iridium, reagent type: catalyst
SMILES stringc1ccc(nc1)-c2ccccc2[Ir](c3ccccc3-c4ccccn4)c5ccccc5-c6ccccn6
Cas Number94928-86-6
This product has met the following criteria: