386529-100ML Display Image

Chlorotrimethylsilane, purified by redistillation, >=99%

Code: 386529-100ML D2-231

Application

Chlorotrimethylsilane (TMSCl) can be used as: A reagent to protect alcohol and amine groups via the formation of trimethylsilyl ethers and trimethylsilyl amines....


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Your Price
£83.00 100ML
£99.60 inc. VAT

Application

Chlorotrimethylsilane (TMSCl) can be used as: A reagent to protect alcohol and amine groups via the formation of trimethylsilyl ethers and trimethylsilyl amines. A catalyst for the preparation of 1,3-diphenyl-2-propenone derivatives (chalcones) as antimicrobial agents. A trapping agent for the anions generated during acyloin condensation reaction. A better alternative catalyst to the toxic mercuric chloride for the activation of samarium (Sm) during the cyclopropanation of both allylic and α-allenic alcohols.A catalyst in the transesterification of triglycerides with alcohols to form fatty acid alkyl esters. A reagent along with lithium bromide for the conversion of alcohols to the corresponding bromides. A reagent in Fischer glycosidation. A source of acid catalyst in the reductive benzylation reaction using benzaldehyde and Et3SiH.A reagent to synthesize sodium trimethylsilanethiolate (Me3SiSNa) by reacting with sodium sulfide, which is an odorless alternative method of synthesizing Me3SiSNa from foul-smelling bis(trimethylsilyl)sulfide and sodium methoxide.

General description

Chlorotrimethylsilane is a chloroorganosilane compound mainly used for silylation reactions.

Packaging

25, 100, 4×100 mL in Sure/Seal™

1, 2 L in Sure/Seal™

assay≥99%
autoignition temp.752 °F
bp57 °C (lit.)
density0.856 g/mL at 25 °C (lit.)
expl. lim.6.4 %
formliquid
impurities﹤0.1% dichlorodimethylsilane
InChI keyIJOOHPMOJXWVHK-UHFFFAOYSA-N
InChI1S/C3H9ClSi/c1-5(2,3)4/h1-3H3
mp−40 °C (lit.)
purified byredistillation, glass distillation
Quality Level200
refractive indexn20/D 1.387 (lit.)
SMILES stringC[Si](C)(C)Cl
vapor density3.7 (vs air)
vapor pressure100 mmHg ( 25 °C)
Code
Description
Unit Size
List Price
Qty
386529-25ML
Unit:25ML
List Price: £21.80
Source:List Price
ADD
386529-1L
Unit:1L
List Price: £310.00
Source:List Price
ADD
Cas Number75-77-4
Hazard Class3
Un Number1298
Pack GroupII
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