Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in studies of the role of excess phosphine ligand in enantioselective conjugate addition of ethylmagnesium bromide and α,β-unsaturated esterReactant serving as a precursor for: Catalysts used for reductive amination of ketones Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters BINAP Pt Dications for cation trapping
(R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It may be employed as chiral catalyst for allylation of N-tosyl α-imino esters.
General description
BINAP is based on a bis naphthalene backbone with different phosphine derivatives. 2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl (p-Tol-BINAP)·AgF complex catalyzed asymmetric Mukaiyama-type aldol reaction is reported.
Legal Information
Sold in collaboration with Takasago for research purposes only.
Packaging
100, 500 mg in amber glass bottle
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