ALD00348-1G Display Image

BOC-3-[3;4-BIS(TRIFLUOROMETHYL)PHENYL]-L

Code: ALD00348-1G D2-231

Application

Unnatural amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tande...


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Application

Unnatural amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).

Other Notes

Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

Packaging

1 g in glass bottle

application(s)peptide synthesis
assay≥95% (HPLC)
descriptionALPH: +24.0, 0.5%EtOH
formpowder or solid
InChI keyLLRXWQAYIGATCH-NSHDSACASA-N
InChI1S/C16H17F6NO4/c1-14(2,3)27-13(26)23-11(12(24)25)7-8-4-5-9(15(17,18)19)10(6-8)16(20,21)22/h4-6,11H,7H2,1-3H3,(H,23,26)(H,24,25)/t11-/m0/s1
Quality Level100
reaction suitabilityreaction type: Boc solid-phase peptide synthesis, reagent type: ligandreaction type: C-H Activation
SMILES stringOC([C@@H](NC(OC(C)(C)C)=O)CC1=CC(C(F)(F)F)=C(C(F)(F)F)C=C1)=O
storage temp.2-8°C
Cas Number2120095-23-8
This product has met the following criteria: