693065-100MG Display Image

-BINAP,

Code: 693065-100MG D2-231

Application

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-BINAP reacts with allylpalladium(II) chloride dimer to form a BINAP-palladium catalyst,...

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£22.60 100MG
List Price

Application

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-BINAP reacts with allylpalladium(II) chloride dimer to form a BINAP-palladium catalyst, which can catalyze the asymmetric allylation of 1,3-diketones to form chiral 2,2-dialkyl-1,3-diketones. It may also be used in the preparation of chirally stabilized rhodium nanoparticles, which can be used as a catalyst for the asymmetric hydroformylation of styrene and vinyl acetate.

Legal Information

Sold in collaboration with Takasago for research purposes only.

Packaging

100, 500 mg in amber glass bottle

InChI keyMUALRAIOVNYAIW-UHFFFAOYSA-N
Quality Level100
InChI1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
optical activity[α]20/D +222°, c = 0.5% in benzene
SMILES stringc1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
mp239-241 °C (lit.)

Code
Description
Unit Size
List Price
Qty
693065-500MG
Unit:500MG
List Price: £63.90
Source:List Price
ADD
Cas Number76189-55-4