665193-3G Display Image

Lanthanum(III) isopropoxide, 98%

Code: 665193-3G D2-231

Application

Complex with an (S,S)-phenyl-linked-binaphthol which promotes a catalytic 1,4-addition of malonate to cyclic and acyclic enones. Co-catalyst wit...


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£250.00 EACH
£300.00 inc. VAT

Application

Complex with an (S,S)-phenyl-linked-binaphthol which promotes a catalytic 1,4-addition of malonate to cyclic and acyclic enones. Co-catalyst with CuF-triphenylphosphine in a general catalytic allylation of ketoimines.

In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome. Solutions of the catalyst should be made using anhydrous solvents and used shortly after preparation.

Packaging

3 g in ampule

500 mg in ampule

assay98%
formsolid
InChI keySORGMJIXNUWMMR-UHFFFAOYSA-N
InChI1S/3C3H7O.La/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
Quality Level100
reaction suitabilitycore: lanthanum, reagent type: catalyst
SMILES stringCC(C)O[La](OC(C)C)OC(C)C
Code
Description
Unit Size
List Price
Qty
665193-500MG
Unit:500MG
List Price: £57.20
Source:List Price
ADD
Cas Number19446-52-7
Hazard Class4.1
Un Number1325
Pack Group2
This product has met the following criteria: