656984-4X25ML Display Image

Isopropylmagnesium chloride lithium chloride complex solution, 1.3 M in THF

Code: 656984-4X25ML D2-231

Application

Reagent for Selective MetalationsUsed for:• Preparation of functionalized acyclic alkenyl magnesium reagents/preparation of 1,2-diketones• Preparation of cyclic a...

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£84.60 EACH
List Price

Application

Reagent for Selective MetalationsUsed for:• Preparation of functionalized acyclic alkenyl magnesium reagents/preparation of 1,2-diketones• Preparation of cyclic alkenyl and dienyl magnesium reagents• Preparation of functionalized triazenes/preparation of carbazoles• Regioselective functionalization of trisubstituted pyridines• Electrophilic amination for preparation of amines• Preparation of Grignards reagents in the presence of masked ketones and aldehydes (using readily deprotectable silylated cyanohydrins)• Preparation of Benzylic Grignards via Sulfur-Magnesium exchange• Functionalization via I-Mg Exchange of unprotected aromatic and heteroaromatic carboxylic acids• Functionalization via I-Mg Exchange of unprotected imidazoles• Pyridyne formation• Functionalization of cyclopentene derivatives• Preparation of 2,3-functionalized furans, benzofurans, and thiophenes• Stereoselective synthesis of substituted cyclopropanes

Reagent used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Product of Albemarle US Inc

Packaging

4×25, 100, 800 mL in Sure/Seal™

2 L in Sure/Seal™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

InChI keyCWTUREABAILGIK-UHFFFAOYSA-L
InChI1S/C3H7.2ClH.Li.Mg/c1-3-2;;;;/h3H,1-2H3;2*1H;;/q;;;2*+1/p-2
SMILES string[Li]Cl.CC(C)[Mg]Cl
density0.951 g/mL at 25 °C
Quality Level100
concentration1.3 M in THF

Code
Description
Unit Size
List Price
Qty
656984-100ML
Unit:100ML
List Price: £82.20
Source:List Price
ADD
656984-800ML
Unit:EACH
List Price: £269.00
Source:List Price
ADD
Cas Number807329-97-1
Hazard Class4.3
Un Number3399
Pack Group2