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2-Methyl-1,5-hexadiene, 97%

Code: 557358-1G D2-231

General description

2-Methyl-1,5-hexadiene on mercury-photosensitized irradiation, undergoes internal cycloaddition to afford 1-methylbicyclo[2.1.1]hexane (as major product)....

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£47.90 1G
List Price

General description

2-Methyl-1,5-hexadiene on mercury-photosensitized irradiation, undergoes internal cycloaddition to afford 1-methylbicyclo[2.1.1]hexane (as major product). High-temperature pyrolysis of 2-methyl-1,5-hexadiene affords 1,5-hexadiene and 2,5-dimethyl-1,5-hexadiene. 2-Methyl-1,5-hexadiene undergoes stereoselective and regioselective reaction with dialkylaluminum chloride (Et2AlCl) and titanium alkoxide [Ti(OPr-i)4, a catalyst] followed by oxidation to afford the corresponding five-membered 3-alkylcycloalkyl methanol. 2-Methyl-1,5-hexadiene is formed as a major product during the condensation reaction between allyl chloride and methallyl chloride in the presence of magnesium.

Packaging

1 g in ampule

SMILES stringCC(=C)CCC=C
InChI1S/C7H12/c1-4-5-6-7(2)3/h4H,1-2,5-6H2,3H3
assay97%
InChI keySLQMKNPIYMOEGB-UHFFFAOYSA-N
refractive indexn20/D 1.417 (lit.)
refractive indexn20/D 1.4170 (lit.)
vapor density﹥1 (vs air)
density0.712 g/mL at 25 °C (lit.)
bp92 °C (lit.)

Cas Number4049-81-4
Hazard Class3
Un Number3295
Pack Group2