225584-100ML Display Image

Vinylmagnesium bromide solution, 1.0 M in THF

Code: 225584-100ML D2-231

Application

Vinylmagnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a L...


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Your Price
£57.40 100ML

Application

Vinylmagnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a Lewis acid.It may also be used in the following transformations: (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenylmethoxy)hex-5-enoate.(R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol.2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol.(4S,5S)-2,2-Dimethyl-5-vinyl[1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol.Ethyl levulinate to ?-methyl-?-vinylbutyrolactone.

Other Notes

Storage below 25°C may cause crystallization. Warm gently to redissolve.

Packaging

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100, 4×100, 800 mL in Sure/Seal™

18 L in Kilo-Lab™

concentration1.0 M in THF
density0.981 g/mL at 25 °C
InChI keyXHHHAXOHMKAOSL-UHFFFAOYSA-M
InChI1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
Quality Level100
reaction suitabilityreaction type: Grignard Reaction
SMILES stringBr[Mg]C=C
Code
Description
Unit Size
List Price
Qty
225584-4X100ML
Unit:EACH
List Price: £152.00
Source:List Price
ADD
225584-800ML
Unit:EACH
List Price: £168.00
Source:List Price
ADD
Cas Number1826-67-1
Hazard Class4.3
Un Number3399
Pack GroupII
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