245305-25G Display Image

(1R)-(-)-Menthyl chloroformate, optical purity ee: 99% (GLC)

Code: 245305-25G D2-231

Application

Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.

Chiral derivatizing agen...

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£105.00 25G
List Price

Application

Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.

Chiral derivatizing agent used for the resolution of alcohols and amines by GC, HPLC, or crystallization.

1R)-(-)-Menthyl chloroformate may be used in the preparation of 1-O-menthoxycarbonyl myo-inositol.

Packaging

25, 100 g in glass bottle

bp108-109 °C/11 mmHg (lit.)
InChI keyKIUPCUCGVCGPPA-KXUCPTDWSA-N
vapor pressure0.01 psi ( 20 °C)
SMILES stringCC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(Cl)=O
refractive indexn20/D 1.458 (lit.)
InChI1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m1/s1
Quality Level100
storage temp.2-8°C
density1.02 g/mL at 25 °C (lit.)
optical purityee: 99% (GLC)
optical activity[α]20/D −83°, c = 1 in chloroform

Code
Description
Unit Size
List Price
Qty
245305-100G
Unit:100G
List Price: £347.00
Source:List Price
ADD
Cas Number14602-86-9
Hazard Class6.1
Un Number3277
Pack Group2